Reversible activation and transfer of white phosphorus by silyl-stannylene

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Sarkar, Debotra and Weetman, Catherine and Munz, Dominik and Inoue, Shigeyoshi (2020) Reversible activation and transfer of white phosphorus by silyl-stannylene. Angewandte Chemie International Edition. ISSN 1521-3773 (https://doi.org/10.1002/anie.202013423)

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Abstract

Use of a silyl supported stannylene ( MesTerSn(Si tBu 3) [ MesTer=2,6-(2,4,6-Me 3C 6H 2) 2C 6H 3] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P 4 complex results in facile P-atom transfer. The computational analysis rationalizes the electronic features and high reactivity of the heteroleptic silyl-substituted stannylene in contrast to the previously reported bis(aryl)stannylene.

ORCID iDs

Sarkar, Debotra, Weetman, Catherine ORCID logoORCID: https://orcid.org/0000-0001-5643-9256, Munz, Dominik and Inoue, Shigeyoshi;
  • Item type:Article
    ID code:74990
    Dates:
    Date
    Event
    5 November 2020
    Published
    5 November 2020
    Published Online
    5 November 2020
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:07 Jan 2021 11:46
    Last modified:11 Nov 2024 12:56
    URI:https://strathprints.strath.ac.uk/id/eprint/74990
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