Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Smith, Charlotte L. and Clowes, Rob and Sprick, Reiner Sebastian and Cooper, Andrew I. and Cowan, Alexander J. (2019) Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst. Sustainable Energy and Fuels, 3 (11). pp. 2990-2994. ISSN 2398-4902 (https://doi.org/10.1039/c9se00450e)

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Abstract

A metal-organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO2 reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO2 concentrations and well defined electrocatalytic sites.

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• Item metadata

  Item type:	Article
  ID code:	74170
  Dates:	Date Event 1 November 2019 Published 9 September 2019 Published Online 8 September 2019 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	08 Oct 2020 14:48
  Last modified:	02 May 2024 22:30
  Related URLs:	Scopus publication https://livrepository.liverpool.ac.uk/30...
  URI:	https://strathprints.strath.ac.uk/id/eprint/74170