Main group multiple bonds for bond activations and catalysis

Weetman, Catherine (2021) Main group multiple bonds for bond activations and catalysis. Chemistry - A European Journal, 27 (6). pp. 1941-1954. ISSN 0947-6539 (https://doi.org/10.1002/chem.202002939)

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Abstract

Since the discovery that the so-called “double-bond” rule could be broken, the field of molecular main group multiple bonds has expanded rapidly. With the majority of homodiatomic double and triple bonds realised within the p-block, along with many heterodiatomic combinations, this Minireview examines the reactivity of these compounds with a particular emphasis on small molecule activation. Furthermore, whilst their ability to act as transition metal mimics has been explored, their catalytic behaviour is somewhat limited. This Minireview aims to highlight the potential of these complexes towards catalytic application and their role as synthons in further functionalisations making them a versatile tool for the modern synthetic chemist.

  • Item type:Article
    ID code:73571
    Dates:
    Date
    Event
    26 January 2021
    Published
    5 August 2020
    Published Online
    5 August 2020
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:12 Aug 2020 13:54
    Last modified:14 Apr 2024 00:53
    URI:https://strathprints.strath.ac.uk/id/eprint/73571
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