Selective reduction of CO2 to a methanol equivalent by B(C6F5)(3)-activated alkaline earth catalysis

Tools

Anker, Mathew D. and Arrowsmith, Merle and Bellham, Peter and Hill, Michael S. and Kociok-Köhn, Gabriele and Liptrot, David J. and Mahon, Mary F. and Weetman, Catherine (2014) Selective reduction of CO2 to a methanol equivalent by B(C6F5)(3)-activated alkaline earth catalysis. Chemical Science, 5 (7). pp. 2826-2830. ISSN 2041-6539 (https://doi.org/10.1039/C4SC00885E)

[thumbnail of Anker-etal-CS2014-Selective-reduction-CO2-methanol-equivalent-B(C6F5)(3)-activated-alkaline-earth-catalysis]
Preview
 Text. Filename: Anker_etal_CS2014_Selective_reduction_CO2_methanol_equivalent_B_C6F5_3_activated_alkaline_earth_catalysis.pdf
Accepted Author Manuscript
License: Creative Commons Attribution-NonCommercial 4.0 logo
Download (512kB)| Preview

Abstract

Treatment of β-diketiminato Mg and Ca amidoborane compounds with B(C6F5)3 induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl)borate derivatives. Both species react with CO2 to provide formate complexes, one of which has been structurally characterised, and may be applied to the highly selective reductive hydroboration of CO2 with pinacolborane (HBpin) to provide the methanol equivalent, CH3OBpin.

ORCID iDs

Anker, Mathew D., Arrowsmith, Merle, Bellham, Peter, Hill, Michael S., Kociok-Köhn, Gabriele, Liptrot, David J., Mahon, Mary F. and Weetman, Catherine ORCID logoORCID: https://orcid.org/0000-0001-5643-9256;
CORE (COnnecting REpositories)