Synthesis and stability of mixed nonfluorinated 1,1,1-trihalo-alkanes

Francisco, C.G. and Gonzalez, C.C. and Kennedy, A.R. and Paz, N.R. and Suarez, E. (2006) Synthesis and stability of mixed nonfluorinated 1,1,1-trihalo-alkanes. Tetrahedron Letters, 47 (1). pp. 35-38. ISSN 0040-4039 (https://doi.org/10.1016/j.tetlet.2005.10.118)

Abstract

1,1,1-Trihaloalkanes of the types R-CCl2I, R-CClBrI, and R-CBr2I belonging to 1,1,1-trihalo-1-deoxy-d-arabinitol series of alditols were prepared and fully characterized by anomeric alkoxyl radical fragmentation of the corresponding 2,2-dihalo-2-deoxy-d-arabino-hexopyranose derivatives. The analogous diiodohalo compounds R-CClI2 and R-CBrI2 could not be prepared by this methodology. The results strongly suggest that the stability of the mixed trihalo alditols decreases with increasing bulkiness of the halogen atoms.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

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• Item metadata

  Item type:	Article
  ID code:	728
  Dates:	Date Event 2 January 2006 Published
  Subjects:	Science > Chemistry Technology > Electrical engineering. Electronics Nuclear engineering
  Department:	Faculty of Engineering > Electronic and Electrical Engineering Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Users 45 not found.
  Date deposited:	07 Apr 2006
  Last modified:	11 Nov 2024 08:34
  URI:	https://strathprints.strath.ac.uk/id/eprint/728