Interfacial concentration effect facilitates heterogeneous nucleation from solution

McKechnie, David and Anker, Samira and Zahid, Saraf and Mulheran, Paul A. and Sefcik, Jan and Johnston, Karen (2020) Interfacial concentration effect facilitates heterogeneous nucleation from solution. Journal of Physical Chemistry Letters, 11 (6). pp. 2263-2271. ISSN 1948-7185

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    Abstract

    Crystal nucleation from solution plays an important role in environmental, biological, and industrial processes and mainly occurs at interfaces, although the mechanisms are not well understood. We performed nucleation experiments on glycine aqueous solutions and found that an oil−solution interface dramatically accelerates glycine nucleation compared to an air−solution interface. This is surprising given that nonpolar, hydrophobic oil (tridecane) would not be expected to favor heterogeneous nucleation of highly polar, hydrophilic glycine. Molecular dynamics simulations found significantly enhanced vs depleted glycine concentrations at the oil−solution vs air−solution interfaces, respectively. We propose that this interfacial concentration effect facilitates heterogeneous nucleation, and that it is due to dispersion interactions. This interface effect is distinct from previously described mechanisms, including surface functionalization, templating, and confinement and is expected to be present in a wide range of solution systems. This work provides new insight that is essential for understanding and controlling heterogeneous nucleation.

    Creators(s): McKechnie, David, Anker, Samira, Zahid, Saraf, Mulheran, Paul A. ORCID logoORCID: https://orcid.org/0000-0002-9469-8010, Sefcik, Jan ORCID logoORCID: https://orcid.org/0000-0002-7181-5122 and Johnston, Karen ORCID logoORCID: https://orcid.org/0000-0002-5817-3479;
    Item type:Article
    ID code:71757
    Keywords:crystal nucleation, glycine aqueous, oil interface, molecular dynamics simulations, heterogeneous nucleation, Chemical engineering, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis
    Subjects:Technology > Chemical engineering
    Department:Faculty of Engineering > Chemical and Process Engineering
    Technology and Innovation Centre > Continuous Manufacturing and Crystallisation (CMAC)
    Technology and Innovation Centre > Bionanotechnology
    Depositing user: Pure Administrator
    Date deposited:12 Mar 2020 14:10
    Last modified:10 Jan 2021 02:35
    URI:https://strathprints.strath.ac.uk/id/eprint/71757
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