The role of organic electron donors in the initiation of BHAS base-induced coupling reactions between haloarenes and arenes

Smith, Andrew J. and Poole, Darren L. and Murphy, John A. (2019) The role of organic electron donors in the initiation of BHAS base-induced coupling reactions between haloarenes and arenes. Science China Chemistry, 62 (11). pp. 1425-1438. ISSN 1869-1870 (https://doi.org/10.1007/s11426-019-9611-x)

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Abstract

Coupling reactions between haloarenes and arenes (including heteroarenes) that are conducted without added transition metals but in the presence of KOtBu or NaOtBu, have been a topic of great interest since their discovery in 2008. Diverse organic structures act as additives that assist these reactions. These additives are converted into organic electron donors by the butoxide base and this leads to initiation of the coupling reactions, which proceed by radical chain mechanisms. This review provides an overview of the initiation stages of these reactions.

ORCID iDs

Smith, Andrew J. ORCID logoORCID: https://orcid.org/0000-0001-7848-076X, Poole, Darren L. and Murphy, John A.;
  • Item type:Article
    ID code:71302
    Dates:
    Date
    Event
    30 November 2019
    Published
    17 October 2019
    Published Online
    9 September 2019
    Accepted
    Keywords:organic electron donor, benzyne, BHAS coupling, electron transfer, potassium tert-butoxide, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:31 Jan 2020 15:09
    Last modified:02 Feb 2022 01:45
    URI:https://strathprints.strath.ac.uk/id/eprint/71302
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