Molecular tilt on monolayer-protected nanoparticles.

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Giomi, L and Bowick, M J and Ma, X. and Majumdar, A. (2012) Molecular tilt on monolayer-protected nanoparticles. EPL (Europhysics Letters), 97 (3). (https://doi.org/10.1209/0295-5075/97/36005)

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Abstract

The structure of the tilted phase of monolayer-protected nanoparticles is investigated by means of a simple Ginzburg-Landau model. The theory contains two dimensionless parameters representing the preferential tilt angle and the ratio epsilon between the energy cost due to spatial variations in the tilt of the coating molecules and that of the van der Waals interactions which favors the preferential tilt. We analyze the model for both spherical and octahedral particles. On spherical particles, we find a transition from a tilted phase, at small epsilon, to a phase where the molecules spontaneously align along the surface normal and tilt disappears. Octahedral particles have an additional phase at small epsilon characterized by the presence of six topological defects. These defective configurations provide preferred sites for the chemical functionalization of monolayer-protected nanoparticles via place-exchange reactions and their consequent linking to form molecules and bulk materials.

ORCID iDs

Giomi, L, Bowick, M J, Ma, X. and Majumdar, A. ORCID logoORCID: https://orcid.org/0000-0003-4802-6720;
  • Item type:Article
    ID code:70890
    Dates:
    Date
    Event
    6 February 2012
    Published
    3 January 2012
    Accepted
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    Subjects:Science > Mathematics
    Department:Faculty of Science > Mathematics and Statistics
    Depositing user: Pure Administrator
    Date deposited:13 Dec 2019 16:31
    Last modified:18 Nov 2024 01:13
    URI:https://strathprints.strath.ac.uk/id/eprint/70890
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