Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure

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Craig, Gavin A. and Sarkar, Arup and Woodall, Christopher H. and Hay, Moya A. and Marriott, Katie E. R. and Kamenev, Konstantin V. and Moggach, Stephen A. and Brechin, Euan K. and Parsons, Simon and Rajaraman, Gopalan and Murrie, Mark (2017) Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure. Chemical Science, 9 (6). pp. 1551-1559. ISSN 2041-6539 (https://doi.org/10.1039/C7SC04460G)

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Abstract

Understanding and controlling magnetic anisotropy at the level of a single metal ion is vital if the miniaturisation of data storage is to continue to evolve into transformative technologies. Magnetic anisotropy is essential for a molecule-based magnetic memory as it pins the magnetic moment of a metal ion along the easy axis. Devices will require deposition of magnetic molecules on surfaces, where changes in molecular structure can significantly alter magnetic properties. Furthermore, if we are to use coordination complexes with high magnetic anisotropy as building blocks for larger systems we need to know how magnetic anisotropy is affected by structural distortions. Here we study a trigonal bipyramidal nickel(ii) complex where a giant magnetic anisotropy of several hundred wavenumbers can be engineered. By using high pressure, we show how the magnetic anisotropy is strongly influenced by small structural distortions. Using a combination of high pressure X-ray diffraction, ab initio methods and high pressure magnetic measurements, we find that hydrostatic pressure lowers both the trigonal symmetry and axial anisotropy, while increasing the rhombic anisotropy. The ligand–metal–ligand angles in the equatorial plane are found to play a crucial role in tuning the energy separation between the dx2−y2 and dxy orbitals, which is the determining factor that controls the magnitude of the axial anisotropy. These results demonstrate that the combination of high pressure techniques with ab initio studies is a powerful tool that gives a unique insight into the design of systems that show giant magnetic anisotropy.

  • Item type:Article
    ID code:69764
    Dates:
    Date
    Event
    19 December 2017
    Published
    18 December 2017
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:12 Sep 2019 11:09
    Last modified:11 Nov 2024 12:26
    URI:https://strathprints.strath.ac.uk/id/eprint/69764
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