Neutral organic super electron donors made catalytic

Rohrbach, Simon and Shah, Rushabh S. and Tuttle, Tell and Murphy, John A. (2019) Neutral organic super electron donors made catalytic. Angewandte Chemie International Edition, 58 (33). pp. 11454-11458. ISSN 1521-3773 (https://doi.org/10.1002/anie.201905814)

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Abstract

Neutral organic super electron donors (SEDs) display impressive reducing power but, until now, it has not been possible to use them catalytically in radical chain reactions. This is because, following electron transfer, these donors form persistent radical cations that trap substrate-derived radicals. This paper unlocks a conceptually new approach to super electron donors that overcomes this issue, leading to the first catalytic neutral organic super electron donor.

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• Item metadata

  Item type:	Article
  ID code:	68821
  Dates:	Date Event 12 August 2019 Published 20 June 2019 Published Online 19 June 2019 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Technology and Innovation Centre > Bionanotechnology
  Depositing user:	Pure Administrator
  Date deposited:	11 Jul 2019 13:58
  Last modified:	11 Nov 2024 12:21
  URI:	https://strathprints.strath.ac.uk/id/eprint/68821