'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode

Theakstone, Ashton and Doeven, Egan H and Conlan, Xavier and Dennany, Lynn and Francis, Paul S (2019) 'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode. Chemical Communications, 55 (49). pp. 7081-7084. ISSN 1359-7345 (https://doi.org/10.1039/C9CC03201K)

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Abstract

A new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy) 3] 2+ and tri-n-propylamine actually arises from anodic reactions at the counter electrode.

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• Item metadata

  Item type:	Article
  ID code:	68043
  Dates:	Date Event 21 June 2019 Published 24 May 2019 Published Online 24 May 2019 Accepted 17 May 2019 Submitted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Strategic Research Themes > Health and Wellbeing Strategic Research Themes > Measurement Science and Enabling Technologies
  Depositing user:	Pure Administrator
  Date deposited:	24 May 2019 13:01
  Last modified:	23 Apr 2024 00:16
  URI:	https://strathprints.strath.ac.uk/id/eprint/68043