'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode

Theakstone, Ashton and Doeven, Egan H and Conlan, Xavier and Dennany, Lynn and Francis, Paul S (2019) 'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode. Chemical Communications, 55 (49). pp. 7081-7084. ISSN 1359-7345

[img] Text (Theakstone-etal-CC-2019-tri-n-propylamine-confirmed-as-emission-at-the-counter-electrode)
Theakstone_etal_CC_2019_tri_n_propylamine_confirmed_as_emission_at_the_counter_electrode.pdf
Accepted Author Manuscript
Restricted to Repository staff only until 24 May 2020.
Download (1MB) | Request a copy from the Strathclyde author

    Abstract

    A new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy) 3] 2+ and tri-n-propylamine actually arises from anodic reactions at the counter electrode.

    Author(s):Theakstone, Ashton, Doeven, Egan H, Conlan, Xavier, Dennany, Lynn ORCID: https://orcid.org/0000-0002-5481-1066 and Francis, Paul S
    Item type:Article
    ID code:68043
    Keywords:electrochemiluminescence (ECL), ruthenium complexes, cathodic mechanism, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Strategic Research Themes > Health and Wellbeing
    Strategic Research Themes > Measurement Science and Enabling Technologies
    Depositing user: Pure Administrator
    Date deposited:24 May 2019 13:01
    Last modified:22 Sep 2019 01:50
    URI:https://strathprints.strath.ac.uk/id/eprint/68043
    Export data:
    CORE (COnnecting REpositories)