'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode
Theakstone, Ashton and Doeven, Egan H and Conlan, Xavier and Dennany, Lynn and Francis, Paul S (2019) 'Cathodic' electrochemiluminescence of [Ru(bpy)3]2+ and tri n propylamine confirmed as emission at the counter electrode. Chemical Communications, 55 (49). pp. 7081-7084. ISSN 1359-7345
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Abstract
A new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy) 3] 2+ and tri-n-propylamine actually arises from anodic reactions at the counter electrode.
Creators(s): |
Theakstone, Ashton, Doeven, Egan H, Conlan, Xavier, Dennany, Lynn ![]() | Item type: | Article |
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ID code: | 68043 |
Keywords: | electrochemiluminescence (ECL), ruthenium complexes, cathodic mechanism, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry Strategic Research Themes > Health and Wellbeing Strategic Research Themes > Measurement Science and Enabling Technologies |
Depositing user: | Pure Administrator |
Date deposited: | 24 May 2019 13:01 |
Last modified: | 21 Jan 2021 10:56 |
URI: | https://strathprints.strath.ac.uk/id/eprint/68043 |
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