Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

Nahra, Fady and Van Hecke, Kristof and Kennedy, Alan and Nelson, David James (2018) Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes. Dalton Transactions. ISSN 1477-9234 (https://doi.org/10.1039/C8DT01506F)

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Abstract

We describe the synthesis and characterisation of a series of new copper and silver complexes with selenourea ligands derived from common and readily-prepared N-heterocyclic carbenes (NHCs). The copper complexes behave somewhat predictably, typically leading to [CuCl(L)] complexes (with two exceptions). The silver complexes display a diverse range of structural motifs, including [AgCl(µ-L)]2, [AgCl(L)2], [Ag(L)2]+, [Ag(L)3]+, and [(Ag(L)2)2(µ-L)]2+ species. All new complexes are characterised by multinuclear NMR spectroscopy, and several examples are characterised by X-ray crystallography. This study demonstrates the diversity of coordination behaviour that these selenourea ligands can engage in.

ORCID iDs

Nahra, Fady, Van Hecke, Kristof, Kennedy, Alan ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Nelson, David James ORCID logoORCID: https://orcid.org/0000-0002-9461-5182;
  • Item type:Article
    ID code:64232
    Dates:
    Date
    Event
    30 May 2018
    Published
    30 May 2018
    Published Online
    30 May 2018
    Accepted
    Keywords:selenourea ligands, copper complexes, silver complexes, N-heterocyclic carbenes (NHCs), multinuclear NMR spectroscopy, X-ray crystallography, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:05 Jun 2018 14:00
    Last modified:25 May 2023 10:11
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/64232
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