Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

He, X.Y. and Noll, B.C. and Beatty, A. and Mulvey, R.E. and Henderson, K.W. (2004) Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126 (24). pp. 7444-7445. ISSN 1520-5126 (http://dx.doi.org/10.1021/ja048750m)

Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

ORCID iDs

Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564

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• Item metadata

  Item type:	Article
  ID code:	638
  Dates:	Date Event 23 June 2004 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	28 Mar 2006
  Last modified:	11 Nov 2024 08:27
  Related URLs:	http://pubs.acs.org/cgi-bin/article.cgi/...
  URI:	https://strathprints.strath.ac.uk/id/eprint/638