Non-aqueous dispersion (NAD) polymerisation-based synthetic route to hypercrosslinked polymer : effect of reaction temperature and solvent system on specific surface area

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Abdullah, Norhayati and Cormack, Peter A.G. (2015) Non-aqueous dispersion (NAD) polymerisation-based synthetic route to hypercrosslinked polymer : effect of reaction temperature and solvent system on specific surface area. Advanced Materials Research, 1134. pp. 198-202. ISSN 1022-6680 (https://doi.org/10.4028/www.scientific.net/AMR.113...)

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Abstract

Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in microsphere form, and were used subsequently in hypercrosslinking reactions. Extensive microporosity was generated in the products, leading to remarkably high inner specific surface areas of up to ~1,500 m2/g. SEM and BET spectroscopy were used to monitor the course of the hypercrosslinking reactions.

ORCID iDs

Abdullah, Norhayati and Cormack, Peter A.G. ORCID logoORCID: https://orcid.org/0000-0002-3390-8176;
  • Item type:Article
    ID code:60888
    Dates:
    Date
    Event
    29 December 2015
    Published
    11 November 2015
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:09 Jun 2017 11:38
    Last modified:11 Nov 2024 11:43
    URI:https://strathprints.strath.ac.uk/id/eprint/60888
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