Soft scorplonate complexes of the fourth and fifth period elements arsenic and tin

Dodds, C.A. and Jagoda, M. and Reglinski, J. and Spicer, M.D. (2004) Soft scorplonate complexes of the fourth and fifth period elements arsenic and tin. Polyhedron, 23 (2-3). pp. 445-450. ISSN 0277-5387 (http://dx.doi.org/10.1016/j.poly.2003.11.032)

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Abstract

We report the synthesis and structure of arsenic (III) and tin(IV) adducts of the hydrotris(methimazolyl)borate anion (Tm-Me). Both species are found to be [E(kappa(3)Tm(Me))(2)](n+) anions (E = As, n = 1; E = Sn, n = 2). Comparisons are made between each of these species and the compounds formed with their heavier and larger group partners bismuth and lead. Due to the remarkable flexibility in the soft scorpionate ligand we were unable to form a charge-separated species analogous to that reported by Parkin for the phenyl analogue (Tm-Ph). Attempts to prepare the tin(II) adduct curiously produced the tin(IV) product [Sn(kappa(3)Tm(Me))(2)][Tm-Me](2) even when the reaction was carried out under inert atmospheres.

ORCID iDs

Dodds, C.A. ORCID logoORCID: https://orcid.org/0000-0002-4590-0307, Jagoda, M., Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168 and Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677;
  • Item type:Article
    ID code:584
    Dates:
    Date
    Event
    22 January 2004
    Published
    Keywords:CRYSTAL-STRUCTURE, TRIPODAL LIGANDS, CHEMISTRY, BISMUTH(III), COORDINATION, THIOUREA, TIN(IV), SODIUM, MODE, HARD, Chemistry, Materials Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Mr Derek Boyle
    Date deposited:20 Mar 2006
    Last modified:20 Jan 2021 16:57
    URI:https://strathprints.strath.ac.uk/id/eprint/584
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