Pushing the frontiers of hard and soft scorpionate chemistry

Dodds, C.A. and Kennedy, A.R. and Reglinski, J. and Spicer, M.D. (2004) Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry, 43 (2). pp. 394-395. ISSN 0020-1669 (http://dx.doi.org/10.1021/ic035167i)

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Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

ORCID iDs

Dodds, C.A. ORCID logoORCID: https://orcid.org/0000-0002-4590-0307, Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168 and Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677;
  • Item type:Article
    ID code:583
    Dates:
    Date
    Event
    26 January 2004
    Published
    Keywords:RAY CRYSTAL-STRUCTURES, TRIPODAL LIGANDS, COMPLEXES, DIHYDRATE, SODIUM, MODE, Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Mr Derek Boyle
    Date deposited:20 Mar 2006
    Last modified:19 May 2023 01:02
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/583
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