Pushing the frontiers of hard and soft scorpionate chemistry

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Dodds, C.A. and Kennedy, A.R. and Reglinski, J. and Spicer, M.D. (2004) Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry, 43 (2). pp. 394-395. ISSN 1520-510X (http://dx.doi.org/10.1021/ic035167i)

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Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

ORCID iDs

Dodds, C.A. ORCID logoORCID: https://orcid.org/0000-0002-4590-0307, Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168 and Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677;
CORE (COnnecting REpositories)