Pushing the frontiers of hard and soft scorpionate chemistry
Dodds, C.A. and Kennedy, A.R. and Reglinski, J. and Spicer, M.D. (2004) Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry, 43 (2). pp. 394-395. ISSN 0020-1669 (http://dx.doi.org/10.1021/ic035167i)
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The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.
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Item type: Article ID code: 583 Dates: DateEvent26 January 2004PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Mr Derek Boyle Date deposited: 20 Mar 2006 Last modified: 08 Apr 2024 15:32 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/583
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