Pushing the frontiers of hard and soft scorpionate chemistry

Dodds, C.A. and Kennedy, A.R. and Reglinski, J. and Spicer, M.D. (2004) Pushing the frontiers of hard and soft scorpionate chemistry. Inorganic Chemistry, 43 (2). pp. 394-395. ISSN 1520-510X (http://dx.doi.org/10.1021/ic035167i)

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Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

ORCID iDs

Dodds, C.A. ORCID logoORCID: https://orcid.org/0000-0002-4590-0307, Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168 and Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677;