Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands

Ojeda-Amador, Ana I. and Martinez-Martinez, Antonio J. and Kennedy, Alan R. and O'Hara, Charles T. (2015) Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands. Inorganic Chemistry, 54 (20). pp. 9833-9844. ISSN 1520-510X (https://doi.org/10.1021/acs.inorgchem.5b01584)

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Abstract

When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.

ORCID iDs

Ojeda-Amador, Ana I. ORCID: https://orcid.org/0000-0003-3991-2851

Kennedy, Alan R. ORCID: https://orcid.org/0000-0003-3652-6015

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• Item metadata

  Item type:	Article
  ID code:	54758
  Dates:	Date Event 19 October 2015 Published 29 September 2015 Published Online 29 September 2015 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	11 Dec 2015 01:29
  Last modified:	21 Dec 2024 01:14
  URI:	https://strathprints.strath.ac.uk/id/eprint/54758