Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes

Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214

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Official URL: http://dx.doi.org/10.1055/s-2005-865238

Abstract

A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.

Creators(s):	Eriksen, H.S., Oyaga, S.C., Sherrington, D.C. and Gibson, C.L. ORCID: https://orcid.org/0000-0003-4948-1266;
Item type:	Article
ID code:	535
Keywords:	asymmetric catalysis, ligands, nucleophilic additions, polymers, supported catalysis, Chemistry, Organic Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Mr Derek Boyle
Date deposited:	16 Mar 2006
Last modified:	05 Aug 2020 00:53
URI:	https://strathprints.strath.ac.uk/id/eprint/535
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