Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes

Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214

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Abstract

A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.

ORCID iDs

Eriksen, H.S., Oyaga, S.C., Sherrington, D.C. and Gibson, C.L. ORCID logoORCID: https://orcid.org/0000-0003-4948-1266;
  • Item type:Article
    ID code:535
    Dates:
    Date
    Event
    17 May 2005
    Published
    Keywords:asymmetric catalysis, ligands, nucleophilic additions, polymers, supported catalysis, Chemistry, Organic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Mr Derek Boyle
    Date deposited:16 Mar 2006
    Last modified:20 Jan 2021 17:04
    URI:https://strathprints.strath.ac.uk/id/eprint/535
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