Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes
Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214
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Abstract
A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.
Creators(s): |
Eriksen, H.S., Oyaga, S.C., Sherrington, D.C. and Gibson, C.L. ![]() | Item type: | Article |
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ID code: | 535 |
Keywords: | asymmetric catalysis, ligands, nucleophilic additions, polymers, supported catalysis, Chemistry, Organic Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 16 Mar 2006 |
Last modified: | 01 Jan 2021 08:15 |
URI: | https://strathprints.strath.ac.uk/id/eprint/535 |
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