Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes

Eriksen, H.S. and Oyaga, S.C. and Sherrington, D.C. and Gibson, C.L. (2005) Polymer-supported beta-amino thioesters as catalysts for the enantioselective addition of diethylzinc to aldehydes. Synlett, 2005 (8). pp. 1235-1238. ISSN 0936-5214 (http://dx.doi.org/10.1055/s-2005-865238)

Abstract

A series of novel polymer-supported thioesters were prepared and found to be effective catalysts for the enantioselective addition of diethylzinc to benzaldehyde. These catalysts gave 1-phenylpropanol in up to 86% ee. The catalysts were fully recyclable and could be used in subsequent additions with retention of the enantioselectivity and efficiency levels.

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• Item metadata

  Item type:	Article
  ID code:	535
  Dates:	Date Event 17 May 2005 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	16 Mar 2006
  Last modified:	08 Apr 2024 15:38
  URI:	https://strathprints.strath.ac.uk/id/eprint/535