Exploring the coordination of cyclic selenoureas to gold(I)

Nelson, David J and Nahra, Fady and Patrick, Scott R and Cordes, David B and Slawin, Alexandra M. Z. and Nolan, Steven P (2014) Exploring the coordination of cyclic selenoureas to gold(I). Organometallics, 33 (13). pp. 3640-3645. ISSN 0276-7333 (https://doi.org/10.1021/om500610w)

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Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π- accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred

ORCID iDs

Nelson, David J ORCID logoORCID: https://orcid.org/0000-0002-9461-5182, Nahra, Fady, Patrick, Scott R, Cordes, David B, Slawin, Alexandra M. Z. and Nolan, Steven P;
  • Item type:Article
    ID code:48956
    Dates:
    Date
    Event
    2014
    Published
    2 July 2014
    Published Online
    27 June 2014
    Accepted
    Keywords:N-heterocyclic carbenes, gold(I), co-ordination chemistry, selenium, ligands, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:15 Jul 2014 08:39
    Last modified:30 Sep 2022 01:24
    URI:https://strathprints.strath.ac.uk/id/eprint/48956
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