Exploring the coordination of cyclic selenoureas to gold(I)
Nelson, David J and Nahra, Fady and Patrick, Scott R and Cordes, David B and Slawin, Alexandra M. Z. and Nolan, Steven P (2014) Exploring the coordination of cyclic selenoureas to gold(I). Organometallics, 33 (13). pp. 3640-3645. ISSN 0276-7333
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Abstract
NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π- accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred
Creators(s): |
Nelson, David J ![]() | Item type: | Article |
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ID code: | 48956 |
Keywords: | N-heterocyclic carbenes, gold(I), co-ordination chemistry, selenium, ligands, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 15 Jul 2014 08:39 |
Last modified: | 20 Jan 2021 21:22 |
URI: | https://strathprints.strath.ac.uk/id/eprint/48956 |
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