Exploring the coordination of cyclic selenoureas to gold(I)

Nelson, David J and Nahra, Fady and Patrick, Scott R and Cordes, David B and Slawin, Alexandra M. Z. and Nolan, Steven P (2014) Exploring the coordination of cyclic selenoureas to gold(I). Organometallics, 33 (13). pp. 3640-3645. ISSN 0276-7333

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Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π- accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred

Creators(s): Nelson, David J ORCID logoORCID: https://orcid.org/0000-0002-9461-5182, Nahra, Fady, Patrick, Scott R, Cordes, David B, Slawin, Alexandra M. Z. and Nolan, Steven P;
Item type:Article
ID code:48956
Keywords:N-heterocyclic carbenes, gold(I), co-ordination chemistry, selenium, ligands, Chemistry, Chemistry(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:15 Jul 2014 08:39
Last modified:25 Sep 2020 04:07
URI:https://strathprints.strath.ac.uk/id/eprint/48956
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