From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

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Manzini, Simone and Nelson, David J. and Lebl, Tomas and Poater, Albert and Cavallo, Luigi and Slawin, Alexandra M Z and Nolan, Steven P. (2014) From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis. Chemical Communications, 50 (17). pp. 2205-2207. ISSN 1359-7345 (https://doi.org/10.1039/c3cc49481k)

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Abstract

The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10).

ORCID iDs

Manzini, Simone, Nelson, David J. ORCID logoORCID: https://orcid.org/0000-0002-9461-5182, Lebl, Tomas, Poater, Albert, Cavallo, Luigi, Slawin, Alexandra M Z and Nolan, Steven P.;
  • Item type:Article
    ID code:47836
    Dates:
    Date
    Event
    28 February 2014
    Published
    10 January 2014
    Published Online
    Subjects:Science > Chemistry
    Department:UNSPECIFIED
    Depositing user: Pure Administrator
    Date deposited:06 May 2014 13:40
    Last modified:11 Nov 2024 10:41
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/47836
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