Electrochemistry and in-situ EPR spectroelectrochemistry of poly(3,4-ethylenedithiothiophene)

Zassowski, Pawel P. and Domagała, Wojciech W. and Łapkowski, Mieczysław S. M.S. and Skabara, Peter J. P.J. (2013) Electrochemistry and in-situ EPR spectroelectrochemistry of poly(3,4-ethylenedithiothiophene). Key Engineering Materials, 559. pp. 121-125. ISSN 1013-9826

Abstract

Polymer films of poly(3,4-ethylenedithiothiophene) obtained by electrochemical oxidative polymerization of the corresponding monomer have been investigated. p-Doping process of the polymer was characterized by in situ EPR spectroelectrochemisty. Compared to its close relative - PEDOT, the polymer features two distinct voltammetric peaks. The results of our studies indicate that both represent faradaic processes and that each manifests generation of charge carriers in the polymer.

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  Item type:	Article
  ID code:	47642
  Dates:	Date Event 12 August 2013 Published
  Keywords:	conducting polymers, EPR, polythiophene, spectroelectrochemistry, Chemistry, Mechanics of Materials, Materials Science(all), Mechanical Engineering
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Technology and Innovation Centre > Photonics University of Strathclyde > University of Strathclyde
  Depositing user:	Pure Administrator
  Date deposited:	25 Apr 2014 09:13
  Last modified:	20 Jan 2021 21:12
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/47642