Electrochemistry and in-situ EPR spectroelectrochemistry of poly(3,4-ethylenedithiothiophene)

Zassowski, Pawel P. and Domagała, Wojciech W. and Łapkowski, Mieczysław S. M.S. and Skabara, Peter J. P.J. (2013) Electrochemistry and in-situ EPR spectroelectrochemistry of poly(3,4-ethylenedithiothiophene). Key Engineering Materials, 559. pp. 121-125. ISSN 1013-9826

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Official URL: https://doi.org/10.4028/www.scientific.net/KEM.559...

Abstract

Polymer films of poly(3,4-ethylenedithiothiophene) obtained by electrochemical oxidative polymerization of the corresponding monomer have been investigated. p-Doping process of the polymer was characterized by in situ EPR spectroelectrochemisty. Compared to its close relative - PEDOT, the polymer features two distinct voltammetric peaks. The results of our studies indicate that both represent faradaic processes and that each manifests generation of charge carriers in the polymer.

Author(s):	Zassowski, Pawel P., Domagała, Wojciech W., Łapkowski, Mieczysław S. M.S. and Skabara, Peter J. P.J. ORCID: https://orcid.org/0000-0001-7319-0464
Item type:	Article
ID code:	47642
Keywords:	conducting polymers, EPR, polythiophene, spectroelectrochemistry, Chemistry, Mechanics of Materials, Materials Science(all), Mechanical Engineering
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry Technology and Innovation Centre > Photonics University of Strathclyde > University of Strathclyde
Depositing user:	Pure Administrator
Date deposited:	25 Apr 2014 09:13
Last modified:	22 Jan 2020 05:27
Related URLs:	Scopus publication
URI:	https://strathprints.strath.ac.uk/id/eprint/47642
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