Nitric oxide species as oxidising agents and adducts for soft scorpionates
Rajasekharan-Nair, R. and Darby, L. and Reglinski, J. and Spicer, M.D. and Kennedy, A.R. (2014) Nitric oxide species as oxidising agents and adducts for soft scorpionates. Inorganic Chemistry Communications, 41. pp. 11-13. ISSN 1387-7003 (https://doi.org/10.1016/j.inoche.2013.12.007)
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Bis-(κ-H,S,S-dihydrobis-(methimazolyl)borato) ruthenium(II), [Ru(Bm)], has been prepared and tested as a nitric oxide scavenger using NO, NOBF and NOBr. The products isolated show that, NO and NO are good one electron oxidising agents towards the ruthenium complexes but NO is not coordinated to the metal. The oxidised species, [Ru(Bm)]BF has been isolated and characterised. Reaction of "Ru(NO)Cl" with NaBm results in the removal of the borohydride from the ligand and formation of [Ru(mtH)(mt)(NO)Cl].
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Item type: Article ID code: 47109 Dates: DateEvent1 March 2014PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 05 Mar 2014 09:39 Last modified: 08 Apr 2024 21:18 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/47109