Biomimetic crystallization of Ag2S nanoclusters in nanopore assemblies
De La Rica, Roberto and Velders, Aldrik (2011) Biomimetic crystallization of Ag2S nanoclusters in nanopore assemblies. Journal of the American Chemical Society, 133 (9). 2875–2877. ISSN 1520-5126 (https://doi.org/10.1021/ja110272g)
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Self-organized nanocrystal architectures with subnanometric spatial resolution were obtained by mimicking the biological crystal growth. The key step of this facile, one-pot, biomimetic route is to induce the self-assembly of the artificial nanopore cucurbit[7]uril with metal ions, which generates supramolecular aggregates that recreate the physicochemical environment of biomineralization processes. The approach holds great promise for the fabrication of nanocrystal superstructures of functional materials, useful in optics, electronics, and catalysis.
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Item type: Article ID code: 45685 Dates: DateEvent2011Published14 February 2011Published OnlineSubjects: Science > Physics Department: Faculty of Science > Physics Depositing user: Pure Administrator Date deposited: 06 Nov 2013 10:43 Last modified: 11 Nov 2024 10:32 URI: https://strathprints.strath.ac.uk/id/eprint/45685