Disorder controlled hole transport in MEH-PPV

Inigo, AR and Chiu, Hsiang-Chih and Fann, Wunshain and Huang, Ying-Sheng and Jeng, U-Ser and Lin, Tsang-Lang and Hsu, Chia-Hung and Peng, Kang-Yung and Chen, Show-An (2004) Disorder controlled hole transport in MEH-PPV. Physical Review B: Condensed Matter and Materials Physics, 69 (7). 075201. ISSN 1098-0121

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Abstract

We analyze the correlation between nanostructure and charge transport in poly(2-methoxy,5-(2'ethyl-hexyloxy)-p-phenylene vinylene) (MEH-PPV) films. The MEH-PPV films prepared in toluene (TL) as well as chlorobenzene (CB) solvents were investigated using the time-of-flight method and x-ray scattering. Nondispersive hole transport was observed at room temperature in devices prepared from both solutions. The field and temperature-dependent mobility were analyzed by the Gaussian disorder transport model. The positional disorder parameter in CB is larger than that in TL films. Both energy and position disorders affect the transport property in the devices from CB whereas only energy disorder affects this property in devices from TL. Correspondingly, according to the x-ray scattering measurements, the TL-cast films have larger chain-packed domains and less order-disorder transition interfaces than those for CB-cast films, along the surface normal, i.e., the charge transport direction.

ORCID iDs

Inigo, AR ORCID logoORCID: https://orcid.org/0000-0002-8776-4008, Chiu, Hsiang-Chih, Fann, Wunshain, Huang, Ying-Sheng, Jeng, U-Ser, Lin, Tsang-Lang, Hsu, Chia-Hung, Peng, Kang-Yung and Chen, Show-An;
  • Item type:Article
    ID code:44408
    Dates:
    Date
    Event
    2 February 2004
    Published
    Keywords:Poly(p-phenylene vinylene)s, molecularly doped polymers, film morphology, interchain interactions, charge-transport, device performance, light-emitting-diodes, polar additives, conjugated polymers, field dependence, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:31 Jul 2013 11:01
    Last modified:20 Jan 2021 20:46
    URI:https://strathprints.strath.ac.uk/id/eprint/44408
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