Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Cave, Dale and Coomer, Fiona and Molinos, Eduardo and Klauss, Hans-Henning and Wood, Paul T (2006) Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O. Angewandte Chemie International Edition, 45 (5). pp. 803-806. ISSN 1433-7851

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Abstract

In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.