Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Cave, Dale and Coomer, Fiona and Molinos, Eduardo and Klauss, Hans-Henning and Wood, Paul T (2006) Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O. Angewandte Chemie International Edition, 45 (5). pp. 803-806. ISSN 1521-3773 (https://doi.org/10.1002/anie.200502847)

Abstract

In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.

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• Item metadata

  Item type:	Article
  ID code:	43262
  Dates:	Date Event 2006 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	18 Mar 2013 15:21
  Last modified:	11 Nov 2024 10:22
  URI:	https://strathprints.strath.ac.uk/id/eprint/43262