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1,4-Dimethylpiperazin-1-ium 3-hydroxy-2-naphthoate

Craig, Gemma E and Johnson, Carla and Kennedy, Alan (2012) 1,4-Dimethylpiperazin-1-ium 3-hydroxy-2-naphthoate. Acta Crystallographica Section E: Structure Reports, 68 (3).

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Abstract

The reaction of 1,4-dimethyl-piperazine and 3-hy-droxy-2-naphthoic acid gives the title 1:1 salt, C(6)H(15)N(2) (+)·C(11)H(7)O(3) (-), with a singly protonated piperazinium cation. In the crystal, a single N-H⋯O hydrogen bond links the cations and anions into discrete pairs and the aromatic anions stack along the crystallographic a-axis direction. This results in layers of cations and anions alternating along the crystallographic c-axis direction. An intra-molecular O-H⋯O hydrogen bond is also present.