Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Henderson, Kenneth W. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1993) Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron, 12 (20). pp. 2535-2538. ISSN 0277-5387 (https://doi.org/10.1016/S0277-5387(00)83080-6)

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Abstract

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

ORCID iDs

Henderson, Kenneth W., Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, Clegg, William and O'Neil, Paul A.;
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