Ionic liquids: novel media for characterisation of radical ions

Marcinek, Andrzej and Zielonka, Jacek and Gebicki, Jerzy and Gordon, Charles M. and Dunkin, Ian R. (2001) Ionic liquids: novel media for characterisation of radical ions. Journal of Physical Chemistry A, 105 (40). pp. 9305-9309. ISSN 1089-5639 (https://doi.org/10.1021/jp0117718)

Abstract

The novel application of ionic liquids as media for radiolytic generation and UV−vis−NIR spectroscopic characterization of radical ions is described. The redox properties of neat 1-butyl-3-methylimidazolium salts and their aqueous solutions have been investigated by means of pulse radiolysis. Furthermore, ionic liquids prove to be ideal media for the simultaneous generation of radical cations and anions. The radical cations generated from 1-methyl-1,4-dihydronicotinamide, a structural analogue of NADH, have been spectroscopically characterized under matrix conditions for the first time.

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• Item metadata

  Item type:	Article
  ID code:	37603
  Dates:	Date Event 2001 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	13 Feb 2012 12:38
  Last modified:	08 Apr 2024 16:24
  URI:	https://strathprints.strath.ac.uk/id/eprint/37603