Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme
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Mulvey, Robert and Clegg, W. and Barr, Donald and Snaith, R. (1986) Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. Polyhedron, 5 (12). pp. 2109-2111. ISSN 0277-5387 (https://doi.org/10.1016/S0277-5387(00)87147-8)
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The diglyme adduct of sodium iodide, NaI·(CH3OCH2CH2)2O, has been structurally characterized by X-ray diffraction. It forms infinite zig-zag chains which, unlike most complexes of the salt, retain NaI bonds. In addition, diglyme molecules bridge pairs of Na atoms through four-co-ordinate O atoms, so representing a new role for this neutral oxygen donor.
ORCID iDs
Mulvey, Robert
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Item type: Article ID code: 37560 Dates: DateEvent1986PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 09 Feb 2012 17:52 Last modified: 05 Jan 2025 04:50 URI: https://strathprints.strath.ac.uk/id/eprint/37560
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