Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands

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BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and SNAITH, R and WRIGHT, D S (1988) Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications (2). pp. 145-147. ISSN 0022-4936 (https://doi.org/10.1039/C39880000145)

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Abstract

The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.

ORCID iDs

BARR, D, DOYLE, M J, Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, RAITHBY, P R, SNAITH, R and WRIGHT, D S;
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