Formation of 1,1-dimethylallyl derivatives by reaction of 3,3-dimethylallyl halides with copper(ii) chelates of acetylacetone and methyl acetoacetate
Miller, J.A. and Black, Rona and Larkin, J. and Nonhebel, D.C. and Wood, H.C.S., Scrimego.C.M (1973) Formation of 1,1-dimethylallyl derivatives by reaction of 3,3-dimethylallyl halides with copper(ii) chelates of acetylacetone and methyl acetoacetate. Journal of the Chemical Society, Perkin Transactions 1 (6). pp. 603-606. ISSN 1472-7781
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Alkylation of the copper(II) chelates of acetylacetone and methyl acetoacetate by 3,3-dimethylallyl halides yields both 3,3-dimethylallyl and 1,1-dimethylallyl products. Formation of 1,1-dimethylallyl derivatives of these -polyketide analogues appears to be the results of a direct C-alkylation, and is a significant characteristic of the copper chelate reactions, which has not been observed previously with other alkylation reactions of -diketones or -keto-esters.
| Author(s): | Miller, J.A., Black, Rona, Larkin, J., Nonhebel, D.C. and Wood, H.C.S. | Item type: | Article |
|---|---|
| ID code: | 36569 |
| Keywords: | 1, 1-dimethylallyl, 3, 3-dimethylallyl halides, copper(ii) chelates, cetylacetone, methyl acetoacetate, Chemical engineering, Physical and theoretical chemistry, Chemistry(all) |
| Subjects: | Technology > Chemical engineering Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Physics |
| Depositing user: | Pure Administrator |
| Date deposited: | 06 Jan 2012 05:24 |
| Last modified: | 03 Jan 2019 12:12 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/36569 |
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