Twelve-connected porous metal–organic frameworks with high H2 adsorption

Jia, J. and Lin, X. and Blake, A. J. and Champness, N. R. and Hubberstey, P. and Walker, G. and Cussen, Eddie and Schroder, M. (2007) Twelve-connected porous metal–organic frameworks with high H2 adsorption. Chemical Communications (London), 2007 (8). pp. 840-842. ISSN 0009-241X

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    Abstract

    The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.