Lithium dimer formation in the li-conducting garnets Li5+xBaxLa3-xTa2O12 (0<x 1.6)

O'Callaghan, Michael P. and Cussen, Eddie (2007) Lithium dimer formation in the li-conducting garnets Li5+xBaxLa3-xTa2O12 (0<x 1.6). Chemical Communications (London), 38 (34). pp. 2048-2050. ISSN 0009-241X

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Abstract

The garnet system Li5+xBaxLa32xTa2O12 shows an unprecedented Li+ content (x ¡ 1.6) and short Li–Li distances of ca2.44A° between majority occupied sites suggesting that the high Li+ mobility requires a complex cooperative mechanism.