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Modular redox-active inorganic chemical cells : iCHELLs

Cooper, Geoffrey and Kitson, Philip and Winter, Ross and Zagnoni, Michele and Long, De-Liang and Cronin, Leroy (2011) Modular redox-active inorganic chemical cells : iCHELLs. Angewandte Chemie, 50 (44). pp. 10373-10376. ISSN 0044-8249

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Abstract

Interfacial membrane formation by cation exchange of polyoxometalates produces modular inorganic chemical cells with tunable morphology, properties, and composition (see picture). These inorganic chemical cells (iCHELLs), which show redox activity, chirality, as well as selective permeability towards small molecules, can be nested within one another, potentially allowing stepwise reactions to occur in sequence within the cell.