Synergistic effects in the activation of small molecules by s-block elements

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O'Hara, Charles; Fairlamb, Ian J S and Lynam, Jason M, eds. (2011) Synergistic effects in the activation of small molecules by s-block elements. In: Organometallic Chemistry. Royal Society of Chemistry, pp. 1-26. ISBN 9781849732802 (https://doi.org/10.1039/9781849732802-00001)

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Abstract

This critical review covers recent developments in the special chemistry which can take place when two different s-block metals are combined within the same organometallic mixture or reagent. It will cover a selection of the most widely researched mixed-metal ‘synergic’ systems, and will be confined to mixed alkali metal/magnesium reagents. An overview of the known structural chemistry of these fascinating systems will be presented along with some of their pertinent, recent uses in synthesis, including, in the activation/cleavage of C-H bonds (i.e., a metallation reaction) or induction of metal-halogen exchange in organic molecules. The chapter begins by providing a brief historical overview of mixed s-block metal chemistry.

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