Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

Kennedy, A R and Mulvey, R E and Rowlings, R B (1998) Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores. Agewandte Chemie-International Edition, 37 (22). pp. 3180-3183. ISSN 1521-3773 (https://doi.org/10.1002/(SICI)1521-3773(19981204)3...)

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Abstract

Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

ORCID iDs

Kennedy, A R ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R E ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Rowlings, R B;
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