Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns
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Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Gemma and Robertson, Stuart (2011) Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. Angewandte Chemie, 50 (36). pp. 8375-8378. ISSN 1521-3773 (https://doi.org/10.1002/anie.201102023)
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The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).
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Kennedy, Alan
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Item type: Article ID code: 34149 Dates: DateEvent19 July 2011PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 20 Oct 2011 13:10 Last modified: 31 Jan 2025 02:36 URI: https://strathprints.strath.ac.uk/id/eprint/34149
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