Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns

Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Gemma and Robertson, Stuart (2011) Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. Angewandte Chemie, 50 (36). pp. 8375-8378. ISSN 1521-3773 (https://doi.org/10.1002/anie.201102023)

Abstract

The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).

ORCID iDs

Kennedy, Alan ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, Robert ORCID: https://orcid.org/0000-0002-1015-2564

Robertson, Stuart ORCID: https://orcid.org/0000-0002-9330-8770

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• Item metadata

  Item type:	Article
  ID code:	34149
  Dates:	Date Event 19 July 2011 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	20 Oct 2011 13:10
  Last modified:	11 Nov 2024 09:52
  URI:	https://strathprints.strath.ac.uk/id/eprint/34149