Homo- and heteroleptic hypersilylcuprates - valuable reagents for the synthesis of molecular compounds with a Cu-Si bond

Klinkhammer, K W and Klett, J and Xiong, Y and Yao, S L (2003) Homo- and heteroleptic hypersilylcuprates - valuable reagents for the synthesis of molecular compounds with a Cu-Si bond. European Journal of Inorganic Chemistry (18). pp. 3417-3424. ISSN 1434-1948 (https://doi.org/10.1002/ejic.200300416)

Abstract

Unsolvated hypersilanides MHyp [Hyp = Si(SiMe3)(3)] of the heavier alkali metals (M-I = Na, K, Cs) react with copper tert-butoxide in toluene to yield crystalline heteroleptic cuprates [M-I(toluene)][tBuOCuHyp]. These cuprates proved to be valuable sources for pure hypersilylcopper and other cuprates bearing hypersilyl ligands such as the di(hypersilyl)cuprates M-I[CuHyp(2)]((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

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  Item type:	Article
  ID code:	33996
  Dates:	Date Event 26 September 2003 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	18 Oct 2011 13:07
  Last modified:	14 Dec 2024 20:54
  URI:	https://strathprints.strath.ac.uk/id/eprint/33996