Ni[((EPPr2)-Pr-i)(2)N](2) complexes : stereolsomers (E = se) and square-planar coordination (E = te)

Levesanos, Nikolaos and Robertson, Stuart D. and Maganas, Dimitrios and Raptopoulou, Catherine P. and Terzis, Aris and Kyritsis, Panayotis and Chivers, Tristram (2008) Ni[((EPPr2)-Pr-i)(2)N](2) complexes : stereolsomers (E = se) and square-planar coordination (E = te). Inorganic Chemistry, 47 (8). pp. 2949-2951. ISSN 1520-510X (https://doi.org/10.1021/ic800272v)

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Abstract

The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

ORCID iDs

Levesanos, Nikolaos, Robertson, Stuart D. ORCID logoORCID: https://orcid.org/0000-0002-9330-8770, Maganas, Dimitrios, Raptopoulou, Catherine P., Terzis, Aris, Kyritsis, Panayotis and Chivers, Tristram;
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