Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity
Garcia, Felipe and Less, Robert J. and McPartlin, Mary and Michalski, Annette and Mulvey, Robert E. and Naseri, Vesal and Stead, Matthew L. and de Vega, Ana Moran and Wright, Dominic S. (2011) Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. Chemical Communications (London), 47 (6). pp. 1821-1823. ISSN 0009-241X (https://doi.org/10.1039/c0cc04483k)
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The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.
ORCID iDs
Garcia, Felipe, Less, Robert J., McPartlin, Mary, Michalski, Annette, Mulvey, Robert E. ORCID: https://orcid.org/0000-0002-1015-2564, Naseri, Vesal, Stead, Matthew L., de Vega, Ana Moran and Wright, Dominic S.;-
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Item type: Article ID code: 33791 Dates: DateEvent2011Published6 December 2010Published OnlineSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 16 Oct 2011 15:07 Last modified: 11 Nov 2024 09:51 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/33791