Azafulvenium methides : new extended dipolar systems

Sutcliffe, O B and Storr, R C and Gilchrist, T L and Rafferty, P and Crew, A P A (2000) Azafulvenium methides : new extended dipolar systems. Chemical Communications (London) (8). pp. 675-676. ISSN 0009-241X (https://doi.org/10.1039/B001521K)

Abstract

The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

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• Item metadata

  Item type:	Article
  ID code:	31970
  Dates:	Date Event 2000 Published 30 March 2000 Published Online
  Keywords:	parameters, silylated acetylenes, Pharmacy and materia medica, Chemistry(all)
  Subjects:	Medicine > Pharmacy and materia medica
  Department:	Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences
  Depositing user:	Pure Administrator
  Date deposited:	13 Jul 2011 08:57
  Last modified:	01 Dec 2022 01:52
  URI:	https://strathprints.strath.ac.uk/id/eprint/31970