Azafulvenium methides : new extended dipolar systems

Sutcliffe, O B and Storr, R C and Gilchrist, T L and Rafferty, P and Crew, A P A (2000) Azafulvenium methides : new extended dipolar systems. Chemical Communications (London) (8). pp. 675-676. ISSN 0009-241X

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Abstract

The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

Author(s):Sutcliffe, O B, Storr, R C, Gilchrist, T L, Rafferty, P and Crew, A P A
Item type:Article
ID code:31970
Keywords:parameters, silylated acetylenes, Pharmacy and materia medica, Chemistry(all)
Subjects:Medicine > Pharmacy and materia medica
Department:Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences
Depositing user: Pure Administrator
Date deposited:13 Jul 2011 08:57
Last modified:03 Jan 2019 12:59
URI:https://strathprints.strath.ac.uk/id/eprint/31970
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