Azafulvenium methides : new extended dipolar systems
Sutcliffe, O B and Storr, R C and Gilchrist, T L and Rafferty, P and Crew, A P A (2000) Azafulvenium methides : new extended dipolar systems. Chemical Communications (London) (8). pp. 675-676. ISSN 0009-241X
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Abstract
The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.
Creators(s): | Sutcliffe, O B, Storr, R C, Gilchrist, T L, Rafferty, P and Crew, A P A; | Item type: | Article |
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ID code: | 31970 |
Keywords: | parameters, silylated acetylenes, Pharmacy and materia medica, Chemistry(all) |
Subjects: | Medicine > Pharmacy and materia medica |
Department: | Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences |
Depositing user: | Pure Administrator |
Date deposited: | 13 Jul 2011 08:57 |
Last modified: | 20 Jan 2021 19:26 |
URI: | https://strathprints.strath.ac.uk/id/eprint/31970 |
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