Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature

Yip, Thomas W.S. and Cussen, E.J. and MacLaren, Donald (2010) Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature. Chemical Communications (London), 46 (5). pp. 698-700. ISSN 0009-241X (https://doi.org/10.1039/B920837B)

[thumbnail of Yip-etal-CC-2010-Synthesis-of-HxLi1-xLaTiO4-from-quantitative]
Preview
Text. Filename: Yip_etal_CC_2010_Synthesis_of_HxLi1_xLaTiO4_from_quantitative.pdf
Accepted Author Manuscript

Download (1MB)| Preview

Abstract

The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH.H2O at room temperature give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

ORCID iDs

Yip, Thomas W.S., Cussen, E.J. ORCID logoORCID: https://orcid.org/0000-0002-2899-6888 and MacLaren, Donald;