Amidine dications : isolation and [fe]-hydrogenase-related hydrogenation

Corr, M.J. and Gibson, K.F. and Kennedy, A.R. and Murphy, J.A. (2009) Amidine dications : isolation and [fe]-hydrogenase-related hydrogenation. Journal of the American Chemical Society, 131 (26). pp. 9174-9175. ISSN 1520-5126 (https://doi.org/10.1021/ja9035847)

Abstract

This commmunication demonstrates the preparation, isolation, and full characterization of superelectrophilic salts based on amidine dications in organic solvent, as their triflate salts. These dications are highly activated toward regiospecific reaction with hydrogen gas under mild conditions in the presence of a metal catalyst (Pd/C), mimicking the behavior of the natural substrate, N-5,N-10-methenyltetrahydromethanopterin, in the iron-sulfur cluster-free [Fe]-hydrogenase.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

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• Item metadata

  Item type:	Article
  ID code:	19070
  Dates:	Date Event 8 July 2009 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	09 Jun 2010 11:43
  Last modified:	11 Nov 2024 09:26
  URI:	https://strathprints.strath.ac.uk/id/eprint/19070