Vibrational spectra of EDTA complexes of divalent tin and lead
Nuttall, R.H. and McConnell, A.A. (1977) Vibrational spectra of EDTA complexes of divalent tin and lead. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 33 (3-4). pp. 459-462. ISSN 1386-1425 (http://dx.doi.org/10.1016/0584-8539(77)80056-1)
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The vibrational spectra of Na2SnEDTA·2H2O and Na2PbEDTA·2H2O in solution, and as solids, suggest that the species present in the two phases are essentially similar. The spectra can be assigned on the basis of a C2υψ-heptaco-ordinate arrangement about the metal. Comparison with the vibrational spectra of binuclear tin and lead complexes suggests that Pb2EDTA has a similar structure to that established for Sn2EDTA·2H2O, but with slight changes in bond distances.
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Item type: Article ID code: 16804 Dates: DateEvent1977PublishedNotes: AHR Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Strathprints Administrator Date deposited: 22 Mar 2010 10:19 Last modified: 08 Apr 2024 17:17 URI: https://strathprints.strath.ac.uk/id/eprint/16804