Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]

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Kennedy, A.R. and Cross, R.J. and Muir, K.W. (1995) Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]. Inorganica Chimica Acta, 231 (1-2). pp. 195-200. ISSN 0020-1693 (http://dx.doi.org/10.1016/0020-1693(94)04321-L)

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Abstract

The synthesis of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P---Ni---P = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.

ORCID iDs

Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Cross, R.J. and Muir, K.W.;
  • Item type:Article
    ID code:1320
    Dates:
    Date
    Event
    15 March 1995
    Published
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user:Users 45 not found.
    Date deposited:28 Jun 2006
    Last modified:11 Nov 2024 08:12
    URI:https://strathprints.strath.ac.uk/id/eprint/1320
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