Scalemic beta-amino sulfide ligands: use in enantioselective conjugate additions and x-ray analysis of a dimeric copper(I) complex

Cran, Graeme A. and Gibson, Colin L. and Handa, Sheetal and Kennedy, Alan R. (1996) Scalemic beta-amino sulfide ligands: use in enantioselective conjugate additions and x-ray analysis of a dimeric copper(I) complex. Tetrahedron: Asymmetry, 7 (9). pp. 2511-2514. ISSN 0957-4166 (http://dx.doi.org/10.1016/0957-4166(96)00320-5)

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Abstract

The enantioselective conjugate addition using a number of scalemic β-amino sulfide ligands to achieve enantiomeric excesses of up to 64% are described together with the X-ray absolute structure analysis of a dimeric copper(I) complex.