Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

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Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X (https://doi.org/10.1016/S0022-328X(97)00549-4)

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Abstract

Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

ORCID iDs

Armstrong, D.R., Craig, F.J., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564;
  • Item type:Article
    ID code:1300
    Dates:
    Date
    Event
    27 April 1998
    Published
    24 March 1997
    Submitted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user:Users 45 not found.
    Date deposited:26 Jun 2006
    Last modified:29 Jan 2025 17:02
    URI:https://strathprints.strath.ac.uk/id/eprint/1300
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