Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II)
Henderson, K.W. and Kennedy, A.R. (1998) Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II). Acta Crystallographica Section C: Crystal Structure Communications, 54 (9). pp. 7816-7824. ISSN 0108-2701
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Abstract
The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].
Author(s): | Henderson, K.W. and Kennedy, A.R. | Item type: | Article |
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ID code: | 1294 |
Keywords: | Mg atom, distorted tetrahedral, amine ligand, magnesium, Chemistry, Biochemistry, Genetics and Molecular Biology(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Catriona Mccallum |
Date deposited: | 27 Jun 2006 |
Last modified: | 03 Jan 2019 11:12 |
URI: | https://strathprints.strath.ac.uk/id/eprint/1294 |
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