Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II)

Henderson, K.W. and Kennedy, A.R. (1998) Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II). Acta Crystallographica Section C: Crystal Structure Communications, 54 (9). pp. 7816-7824. ISSN 0108-2701 (http://dx.doi.org/10.1107/S0108270198003655)

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Abstract

The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].

ORCID iDs

Henderson, K.W. and Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015;
  • Item type:Article
    ID code:1294
    Dates:
    Date
    Event
    1998
    Published
    Keywords:Mg atom, distorted tetrahedral, amine ligand, magnesium, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Catriona Mccallum
    Date deposited:27 Jun 2006
    Last modified:20 Jan 2021 16:42
    URI:https://strathprints.strath.ac.uk/id/eprint/1294
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