Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II)

Henderson, K.W. and Kennedy, A.R. (1998) Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II). Acta Crystallographica Section C: Crystal Structure Communications, 54 (9). pp. 7816-7824. ISSN 0108-2701

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Abstract

The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].

Author(s):Henderson, K.W. and Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015
Item type:Article
ID code:1294
Keywords:Mg atom, distorted tetrahedral, amine ligand, magnesium, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Catriona Mccallum
Date deposited:27 Jun 2006
Last modified:23 Jan 2020 01:28
URI:https://strathprints.strath.ac.uk/id/eprint/1294
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